Clean separation and purification for strategic metals of molybdenum …
The volume of feed wastewater (250 L) was reduced by ∼94%, and the molybdenum concentration was increased from 1.32 to 10.2 g/L using a VNF-1 membrane for its smooth recovery (98.7%) as ammonium molybdate by chemical precipitation under response-surface-optimized conditions of critical parameters of NH 4 + /Mo ratio (1.32), …
Extraction of molybdenum and nickel from Ni–Mo ore by …
The nickel and molybdenum were extracted by acid leaching under oxygen pressure. Compared with traditional roasting methods, this hydrometallurgical method eliminates SO 2 and As 2 O 3 emission (the Ni–Mo ore containing 15%–25% S). Compared with existing alkali leaching recovery of molybdenum process, almost all the nickel and …
Selective recovery of molybdenum from spent HDS catalyst …
Recovery of molybdenum was largely dependent on the concentrations of Na 2 CO 3 and H 2 O 2 in the reaction medium, which in turn controls the pH of leach liquor and the presence of Al and Ni as impurities. ... An alternative to this is the treatment of spent catalyst by simple process, which contributes to the solution of environmental related ...
Recovery of vanadium from spent catalysts and alumina …
The various process options available to recover vanadium from spent dehydrosulphurisation catalysts, sulphuric acid catalysts, and alumina sludge residues from the Bayer Process are reviewed, and the fate of other metal impurities such as Mo, Ni, Co, Al and Fe are considered. Most processes give an impure V 2 O 5 product, but selective …
Potential of electrolytic processes for recovery of molybdenum …
@article{osti_1892431, title = {Potential of electrolytic processes for recovery of molybdenum from molten salts for 99Mo production}, author = {Moon, Jisue and Myhre, Kristian and Andrews, Hunter and McFarlane, Joanna}, abstractNote = {Molten salt reactor (MSR) technologies are receiving significant interest for commercialization because of …
Recovery of Molybdenum from Metallurgical Wastewater …
Molybdenum is one of the essential trace elements for the survival of plants and animals, and it is also an important strategic resource in the development of the national economy [1, 2].However, in the mining and metallurgical processing of Mo minerals, there is a large amount of ultra-low concentration Mo-containing wastewater, which is difficult to …
Review of Molybdenum Recovery Processes | JOM
Review of Molybdenum Recovery Processes | JOM. JOM - Our purpose in this paper is to review present molybdenum recovery processes from a historical …
Full article: Highly efficient recovery of molybdenum …
Based on the obtained results, an optimized extraction and stripping process was proposed to recycle molybdenum from spent catalyst …
Leaching and recovery of molybdenum, nickel and …
2 Leaching and Recovery of Molybdenum from Spent Catalysts 9 2.1. Introduction 10 2.2. General Characteristics of Molybdenum 13 2.2.1. Origin, abundance and production of molybdenum 13 2.2.2. Equilibria and complexes of molybdenum 14 2.2.3. Molybdenum in catalysts 17 2.3. Chemical Leaching of Molybdenum from Spent Catalysts 18 2.3.1.
Highly efficient sorption of molybdenum from tungstate …
The sorption process conforms to Langmuir isotherm models and the quasi-second-order kinetic model. The sorption mechanism was also discussed, which was a single layered spontaneous sorption process. ... a mixture of D301 resin and TOA was explored to separate and recovery molybdenum from tungstate solution in the present …
A novel membrane-integrated sustainable technology for …
An experimental investigation was conducted to recover and recycle a precious metal (molybdenum) while treating industrial wastewater using a novel membrane-integrated hybrid technology.Hollow-fiber crossflow modules containing ultrafiltration and nanofiltration membranes in the recirculation mode successfully …
Recovery of high specific activity molybdenum-99 …
The process leverages a novel solvent extraction scheme to recover Mo using di (2-ethylhexyl) phosphoric acid following uranium and transuranics removal with …
Extraction of molybdenum by a supported liquid membrane method
Then, leaching of molybdenite concentrates and recovery of dissolved metals by solvent extraction (henceforth abbreviated as SX) has, therefore, become important as a promising industrial process. The residual solutions generated in these leaching and SX steps contain variable but significant concentrations of molybdenum, …
Comprehensive Electrochemical-Chemical Study of Copper
For recovery of the leached copper, the precipitation process was done by the addition of Na2S at 45 °C, S/Cu = 1, and pH = 9. Molybdenite is the most important molybdenum concentrate, which is mainly recovered as a …
Extraction of selected metals from spent
ABSTRACT The aim of present study is to examine the dissolution and kinetics of valuable metals from spent hydrodesulfurization catalyst using potassium hydroxide. Due to low solubility of metal oxides of Ni and Co in alkali medium, only the recovery of Mo and Al was investigated. Optimum roasting temperature and time were determined 600°C and 60 …
Highly efficient recovery of molybdenum from …
Among the hydrometallurgical processes, solvent extraction was considered as an eficient method to recover molybdenum, it is widely used in practical pro- duction due to its …
Recovery of Molybdenum with Sodium-Carbonate …
An alternative, integrated method for processing sulfide molybdenum concentrate to recover molybdenum and associated rhenium is proposed. The method …
Green separation and recovery of molybdenum from
Separation of molybdenum (Mo) from tungstate solution has become a bottleneck issue in tungsten (W) metallurgy and did hinder the development of high purity tungsten materials. The traditional Mo removal methods using Na 2 S, NaHS as vulcanizing reagent are suffering the environmental issues of toxic H 2 S gas and molybdenum …
Hydrometallurgical Molybdenum Recovery from …
Abstract. In this study, a green and sustainable hydrometallurgical process, based on soft acid derived from agrifood waste as a byproduct, is used to recover …
Extraction and Recovery of Metals from Spent HDS …
(HDS) catalysts. The process put together stages already known in the technical literature, tested again with samples coming from the roasting stage in a pilot kiln, which is the most limiting stage of metal recovery from spent catalysts. These catalysts contain valuable metals such as cobalt (Co), molybdenum (Mo), nickel (Ni), and …
An environmentally friendly method for extraction of cobalt …
Although extremely high cobalt/molybdenum recovery rates were obtained with a shorter reaction duration in DES-1, 48-h reaction durations for both DES may be appropriate. ... Beolchini F (2013) An environmentally friendly process for the recovery of valuable metals from spent refinery catalysts. Waste Manag Res J a Sustain Circ Econ …
Recovery of molybdenum, cobalt and nickel from spent
The spent hydrodesulphurization (HDS) catalyst is an important secondary source for Ni, Mo, Co and Al metals. The high yield recovery of these metals is quite difficult due to the carbon accumulated on the catalyst surface and the stability of the metal oxides.Therefore, the leaching process in the presence of sodium persulfate (Na 2 S 2 O …
Extraction of molybdenum from a spent HDS catalyst using …
This paper describes the recovery of molybdenum from a spent CoMo/Al2O3 by soda leaching after a roasting step. First, the leaching was performed on a catalyst industrially roasted at 800 °C ...
Recovery of Molybdenum with Sodium-Carbonate …
The recovery of molybdenum in the solution is more than 98%. With increase in the concentration of soda, the recovery of molybdenum decreases because of the formation of binary carbonates of sodium calcium. The concentration of molybdenum in such solutions is 32.45 g/dm 3, the main impurities being sodium and sulfur. …
Highly efficient sorption of molybdenum from …
and recovery molybdenum from tungstate solution in the present study. The sorption dynamics and sorption mechanism were investigated. According to the quantum mechanical module of Materials Studio so ware, the Mulliken population was calculated, and the sorption mechanism by modi ed D301 was obtained. Besides, optimization of sorption process
Molybdenite flotation from copper/molybdenum …
appropriate for the evaluation of the ozone conditioning process. Both samples were final flotation products from the respective copper flotation circuits and were taken before entering the molybdenum circuit. The Morenci copper/molybdenum concentrate analyzed 0.2%-0.4% Mo and 28%-33% Cu, while the grade of the Copperton copper/molybdenum ...
Metals | Free Full-Text | Extraction and Recovery of Metals …
The process put together stages already known in the technical literature, tested again with samples coming from the roasting stage in a pilot kiln, which is the most limiting stage of metal recovery from spent catalysts. These catalysts contain valuable metals like cobalt (Co), molybdenum (Mo), nickel (Ni), and vanadium (V).
Stepwise separation and recovery of molybdenum, …
Recovering metal values in hazardous spent hydrogenation catalysts is of vital economic and environmental importance. Herein, the selective recovery of valuable molybdenum (Mo), vanadium (V), and nickel (Ni) from spent hydroprocessing catalysts are achieved by using a sulfuric acid leaching-stepwise extraction process. After roasting in …
Separation of vanadium, tungsten and molybdenum from …
Bayer vanadium sludge, as a by-product generated from the Bayer process, is a potential secondary resource for vanadium recovery. To alleviate the problems of reagent consumption and effluent treatment presented in vanadium extraction processes, a novel and sustainable process featuring phosphate removal by CaCO 3, vanadium …
Recovery of molybdenum by solvent extraction from …
Abstract In this study, simple and a rapid solvent extraction method is investigated to recover Mo(VI) from simulated HLLW. The (NH4)6Mo7O24·4H2O dissolved in 3 M HNO3 was treated with ascorbic acid and KSCN to form orange red colored Mo(V)-SCN. Reduction of Mo(VI) was confirmed by cyclic voltammetry. The freshly formed …
